Accurate Molecular Structures by Domenicano, Aldo; Hargittai, István;

Their Determination and Importance

Sorozatcím: International Union of Crystallography Monographs on Crystallography; 1;

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A termék adatai:

Kiadó OUP Oxford
Megjelenés dátuma 1992. március 19.

ISBN 9780198555568
Kötéstípus Keménykötés
Terjedelem602 oldal
Méret 241x160x38 mm
Súly 1072 g
Nyelv angol
Illusztrációk numerous line illustrations, tables

Kategóriák

Analitikai kémia Fizikai kémia Ásványtan és kristálytan További könyvek a kémia területén

Rövid leírás:

Modern experimental and computational techniques are capable of determining bond lengths and angles with precisions of a few thousandths of an oangström and a few tenths of a degree. Such precisions are meaningful only if they are coupled with rigorous error analysis and careful evaluation of the physical meaning of the parameters.

This book demonstrates the meaning and applicability of accurate structures and their variations, following a rigorous exposure of the demands in their determination. It establishes guidelines for accuracy requirements in answering broadly varying questions in current chemical research.

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Hosszú leírás:

Modern experimental and computational techniques are capable of determining bond lengths and angles with precisions of a few thousandths of an oangström and a few tenths of a degree. Such precisions are meaningful only if they are coupled with rigorous error analysis and careful evaluation of the physical meaning of the parameters.

Here, internationally respected authors present all modern experimental and computational techniques for the determination of accurate molecular structures for the first time in one volume. They establish guidelines for accuracy requirements in answering broadly varying questions in current chemical research.

. . . an important book which will remain the standard work for teachers, students, and researchers for years to come.

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Tartalomjegyzék:

Structural Chemistry
The Potential Energy Surface and the Meaning of Internuclear Distances
Reliability of Structure Determinations by Microwave Spectroscopy
Determination of Accurate Molecular Structure by Vibration-Rotation Spectroscopy
Gas-phase Electron Diffraction
X-ray Crystallography: An Introduction
Measurement of Accurate Bragg Intensities
Diffraction Studies of Molecular Motion in Crystals
Lattice-dynamical Interpretation of Crystallographic Thermal Parameters
The Role of Electron Density in X-ray Crystallography
Accurate Crystal Structure Analysis by Neuron Diffraction
Nuclear Magnetic Resonance Spectroscopy and Precise Molecular Geometries
Quantum Mechanical Determination of Static and Dynamic Structure
Molecular Mechanics
Crystallographic Databases: Retrieval and Analysis of Precise Structural Information From the Cambridge Structural Database
The Importance of Accurate Structure Determination in Organic Chemistry
Structure Correlations, Reaction Pathways and Energy Surfaces for Chemical Reactions
Structural Substituent Effects in Benzene Derivatives
Effect of Crystal Environment on Molecular Structures
The Importance of Accurate Structure Determination in Inorganic Chemistry
Structural variability in metal cluster compounds