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  • Surfactants: In Solution, at Interfaces and in Colloidal Dispersions

    Surfactants by Aveyard, Bob;

    In Solution, at Interfaces and in Colloidal Dispersions

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    A termék adatai:

    • Kiadó OUP Oxford
    • Megjelenés dátuma 2019. október 15.

    • ISBN 9780198828600
    • Kötéstípus Keménykötés
    • Terjedelem576 oldal
    • Méret 247x178x34 mm
    • Súly 1258 g
    • Nyelv angol
    • Illusztrációk 297 grayscale and 57 color line drawings, 16 grayscale halftones and 7 color halftones
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    Rövid leírás:

    Surfactants are in everyday products such as detergents, foodstuffs, and cosmetics. Their molecules have one part which is water soluble and another which is not. This gives them two valuable properties: they adsorb at surfaces, and they stick together in water. This book treats the physical chemistry and physics underlying surfactants.

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    Hosszú leírás:

    Surfactants... today you have probably eaten some, or rubbed others on your body. Plants, animals (including you) and microorganisms make them, and many everyday products (e.g. detergents, cosmetics, foodstuffs) contain them. Surfactant molecules have one part which is soluble in water and another which is not. This gives surfactant molecules two valuable properties: 1) they adsorb at surfaces (e.g. of an oil droplet in water), and 2) they stick together (aggregate) in water. The aggregates (micelles) are able to dissolve materials not soluble in water alone, and adsorbed surfactant layers, at the surfaces of particles or (say) oil droplets in water, stop the particles or drops sticking together. This is why stable emulsions such as milk do not separate into layers. This book treats the basic physical chemistry and physics underlying the behaviour of surfactant systems.

    In this book, you will first learn about some background material including hydrophobic hydration, interfacial tension and capillarity (Section I). Discussion of surfactant adsorption at liquid/fluid and solid/liquid interfaces is given in Section II, and includes thermodynamics of adsorption, dynamic and rheological aspects of liquid interfaces and the direct characterisation of surfactant monolayers. In Section III, a description is given of surfactant aggregation to give micelles, lyotropic liquid crystals, microemulsions and Winsor systems. There follows a discussion of surface forces and the way they confer stability on lyophobic colloids and thin liquid films (Section IV). Various dispersions stabilised by adsorbed surfactant or polymer (including solid in liquid dispersions, emulsions and foams) are considered in Section V. The wetting of solids and liquids is explored in Section VI. Like surfactants, small solid particles can adsorb at liquid/fluid interfaces, form monolayers and stabilise emulsions and foams. Such behaviour is covered in Section VII. It is assumed the reader has a knowledge of undergraduate physical chemistry, particularly chemical thermodynamics, and of simple physics. Mathematics (elementary algebra and calculus) is kept at a level consistent with the straightforward derivation of many of the equations presented.

    I recommend this book not only to undergraduates, graduates and PhD students in colloid and interface science and related areas, but also to researchers in this field. Even established experts will find new insights into the various areas of surfactant science. I am sure readers will be inspired by the way the world of surfactants and their behaviour is presented here.

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    Tartalomjegyzék:

    SECTION I BACKGROUND
    What are surfactants?
    Oil and water do not mix: hydrophobic hydration
    Capillarity, wetting and surface (interfacial) tension
    SECTION II ADSORPTION OF SURFACTANTS
    Adsorption of surfactants at liquid interfaces: thermodynamics
    Adsorption of surfactants at liquid/vapour and liquid/liquid interfaces
    Dynamic aspects of liquid interfaces
    Adsorption of surfactants at solid/liquid interfaces
    Direct characterisation of adsorbed surfactant layers
    SECTION III: AGGREGATION OF SURFACTANTS IN SOLUTION
    Aggregation of surfactants in aqueous systems
    Surfactants in systems with oil and water, including microemulsions
    Section IV: SURFACE FORCES AND THIN LIQUID FILMS
    Surface forces and colloidal behaviour
    Thin liquid films
    SECTION V: DISPERSIONS STABILISED BY SURFACTANTS
    Dispersions of solids in liquids
    Emulsions and Foams
    Rheology of colloids
    SECTION VI: WETTING OF SOLIDS AND LIQUIDS
    Wetting
    SECTION VII: SYSYEMS WITH PARTICLES AT LIQUID INTERFACES
    Particles in Monolayers and Thin Liquid Films
    Emulsions stabilised by solid particles
    THEMES AND CONNECTIONS

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