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  • Physical and Chemical Kinetics

    Physical and Chemical Kinetics by Berry, R. Stephen; Rice, Stuart A.; Ross, John;

    Sorozatcím: Topics in Physical Chemistry;

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    A termék adatai:

    • Kiadás sorszáma 2
    • Kiadó OUP USA
    • Megjelenés dátuma 2001. október 18.

    • ISBN 9780195147506
    • Kötéstípus Keménykötés
    • Terjedelem276 oldal
    • Méret 213x269x20 mm
    • Súly 961 g
    • Nyelv angol
    • Illusztrációk numerous line figures
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    Rövid leírás:

    This is a textbook for courses in Quantum Mechanics using one of three parts of the textbook, Physical Chemistry, 2/e, by Berry, Rice, and Ross (OUP 2000). This text is designed for a Senior/Graduate (4th/5th) year college course commonly called introduction to Quantum Mechanics. The course assumes a strong preparation in general chemistry and probably a course in physical chemistry. The solutions to the odd problems will be bound in the book as the final appendix.

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    Hosszú leírás:

    Physical and Chemical Kinetics concludes the three-volume set of Physical Chemistry, Second Edition, by R. Stephen Berry, Stuart A. Rice, and John Ross (OUP 2000). With the same precision and efficiency as the other two volumes, Physical and Chemical Kinetics discusses the elements of physical and chemical kinetics and presents advanced discussions of unimolecular reactions, kinetics of photochemically induced reactions, chain reactions, nonlinear phenomena, fluctuations in chemical kinetics, symmetry rules for chemical reactions, catalysis, and the kinetics of electrode reactions. Up-to-date and thorough, this valuable reference provides the cutting-edge information and theory that today's students and researchers need to understand past scientific accomplishments as well as to make future contributions to the field of physical chemistry.

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    Tartalomjegyzék:

    Preface
    PART III: PHYSICAL AND CHEMICAL KINETICS
    27. Molecular Motion and Collisions
    Kinematics
    Forces and Potentials
    Collision Dynamics
    Types of Collisions
    Scattering Cross Sections
    Elastic Scattering of Hard Spheres
    Elastic Scattering of Atoms
    Quantum Mechanical Scattering
    28. The Kinetic Theory of Gases
    Distribution Functions
    Collision Frequency in a Dilute Gas
    The Evolution of Velocity Distributions in Time
    The Maxwell-Boltzmann Distribution
    Collision Frequency for Hard-Sphere Molecules
    Molecular Fluxes of Density, Momentum Density, and Energy Density
    Effusion
    Transport Properties of Gases
    Energy Exchange Processes
    Sound Propagation and Absorption
    29. The Kinetic Theory of Dense Phases
    Transport Properties in Dense Fluids
    Some Basic Aspects of Brownian Motion
    Stochastic Approach to Transport
    Autocorrelation Functions and Transport Coefficients
    Transport in Solids
    Electrical Conductivity in Electrolyte Solutions
    30. Chemical Kinetics
    General Concepts of Kinetics
    Interactions between Reactive Molecules
    Vignette: Quantum Mechanical Computations of Potential Energy Hypersurfaces, by H.F. Schaefer III
    Collisions between Reactive Molecules
    Vignette: Femtochemistry--Reaction Dynamics with Atomic Resolution, by A.H. Zewail
    Hard-Sphere Collision Theory: Reactive Cross Sections
    Hard-Sphere Collision Theory: The Rate Coefficient
    Activated-Complex Theory
    Vignette: Present- Day View of Transition State Theory, by D.G. Truhlar
    Activated-Complex Theory: Thermodynamic Interpretation
    Theory of Reaction Kinetics in Solution
    Vignette: Kramers' Theory of Reactions in Solutions, by M.O. Vlad and J. Ross
    Vignette: Chemical Reactions in Condensed Phases, by P.G. Wolynes
    Linear Free-Energy Relationships
    Experimental Methods in Kinetics
    Analysis of Data for Complex Reactions
    Mechanisms of Chemical Reactions
    Bimolecular Reactions
    Vignette: Electron Transfer Reactions, by R.A. Marcus
    Uniomolecular Reactions
    Termolecular Reactions
    31. Some Advanced Topics in Chemical Kinetics
    More about Unimolecular Reactions
    Kinetics of Photochemically Induced Reactions
    Chain Reactions
    Nonlinear Phenomena
    Fluctuations in Chemical Kinetics
    Symmetry Rules for Chemical Reactions
    Introduction to Catalysis
    Enzyme Catalysis
    Acid-Base Catalysis
    Metal-Ion Complex and Other Types of Homogeneous Catalysis
    Heterogeneous Reactions: Adsorption of Gas on a Surface
    Heterogeneous Catalysis
    Kinetics of Electrode Reactions (a Vignette by C.E.D. Chidsey)
    Vignette: Applications of Physical Chemistry: A Biological Example, by B. Eisenberg
    Appendices
    Systems of Units
    Partial Derivatives
    Glossary of Symbols
    Searching the Scientific Literature
    Index

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