Physical and Chemical Kinetics
Series: Topics in Physical Chemistry;
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Product details:
- Edition number 2
- Publisher OUP USA
- Date of Publication 18 October 2001
- ISBN 9780195147506
- Binding Hardback
- No. of pages276 pages
- Size 213x269x20 mm
- Weight 961 g
- Language English
- Illustrations numerous line figures 0
Categories
Short description:
This is a textbook for courses in Quantum Mechanics using one of three parts of the textbook, Physical Chemistry, 2/e, by Berry, Rice, and Ross (OUP 2000). This text is designed for a Senior/Graduate (4th/5th) year college course commonly called introduction to Quantum Mechanics. The course assumes a strong preparation in general chemistry and probably a course in physical chemistry. The solutions to the odd problems will be bound in the book as the final appendix.
MoreLong description:
Physical and Chemical Kinetics concludes the three-volume set of Physical Chemistry, Second Edition, by R. Stephen Berry, Stuart A. Rice, and John Ross (OUP 2000). With the same precision and efficiency as the other two volumes, Physical and Chemical Kinetics discusses the elements of physical and chemical kinetics and presents advanced discussions of unimolecular reactions, kinetics of photochemically induced reactions, chain reactions, nonlinear phenomena, fluctuations in chemical kinetics, symmetry rules for chemical reactions, catalysis, and the kinetics of electrode reactions. Up-to-date and thorough, this valuable reference provides the cutting-edge information and theory that today's students and researchers need to understand past scientific accomplishments as well as to make future contributions to the field of physical chemistry.
MoreTable of Contents:
Preface
PART III: PHYSICAL AND CHEMICAL KINETICS
27. Molecular Motion and Collisions
Kinematics
Forces and Potentials
Collision Dynamics
Types of Collisions
Scattering Cross Sections
Elastic Scattering of Hard Spheres
Elastic Scattering of Atoms
Quantum Mechanical Scattering
28. The Kinetic Theory of Gases
Distribution Functions
Collision Frequency in a Dilute Gas
The Evolution of Velocity Distributions in Time
The Maxwell-Boltzmann Distribution
Collision Frequency for Hard-Sphere Molecules
Molecular Fluxes of Density, Momentum Density, and Energy Density
Effusion
Transport Properties of Gases
Energy Exchange Processes
Sound Propagation and Absorption
29. The Kinetic Theory of Dense Phases
Transport Properties in Dense Fluids
Some Basic Aspects of Brownian Motion
Stochastic Approach to Transport
Autocorrelation Functions and Transport Coefficients
Transport in Solids
Electrical Conductivity in Electrolyte Solutions
30. Chemical Kinetics
General Concepts of Kinetics
Interactions between Reactive Molecules
Vignette: Quantum Mechanical Computations of Potential Energy Hypersurfaces, by H.F. Schaefer III
Collisions between Reactive Molecules
Vignette: Femtochemistry--Reaction Dynamics with Atomic Resolution, by A.H. Zewail
Hard-Sphere Collision Theory: Reactive Cross Sections
Hard-Sphere Collision Theory: The Rate Coefficient
Activated-Complex Theory
Vignette: Present- Day View of Transition State Theory, by D.G. Truhlar
Activated-Complex Theory: Thermodynamic Interpretation
Theory of Reaction Kinetics in Solution
Vignette: Kramers' Theory of Reactions in Solutions, by M.O. Vlad and J. Ross
Vignette: Chemical Reactions in Condensed Phases, by P.G. Wolynes
Linear Free-Energy Relationships
Experimental Methods in Kinetics
Analysis of Data for Complex Reactions
Mechanisms of Chemical Reactions
Bimolecular Reactions
Vignette: Electron Transfer Reactions, by R.A. Marcus
Uniomolecular Reactions
Termolecular Reactions
31. Some Advanced Topics in Chemical Kinetics
More about Unimolecular Reactions
Kinetics of Photochemically Induced Reactions
Chain Reactions
Nonlinear Phenomena
Fluctuations in Chemical Kinetics
Symmetry Rules for Chemical Reactions
Introduction to Catalysis
Enzyme Catalysis
Acid-Base Catalysis
Metal-Ion Complex and Other Types of Homogeneous Catalysis
Heterogeneous Reactions: Adsorption of Gas on a Surface
Heterogeneous Catalysis
Kinetics of Electrode Reactions (a Vignette by C.E.D. Chidsey)
Vignette: Applications of Physical Chemistry: A Biological Example, by B. Eisenberg
Appendices
Systems of Units
Partial Derivatives
Glossary of Symbols
Searching the Scientific Literature
Index
