Sulfuric Acid Manufacture
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Product details:
- Publisher Elsevier Science
- Date of Publication 4 November 2005
- ISBN 9780080444284
- Binding Hardback
- No. of pages425 pages
- Size 241x165 mm
- Weight 1110 g
- Language English 0
Categories
Long description:
More sulfuric acid is produced every year than any other chemical. It has a wide range of uses including phosphate fertilizer production, explosives, glue, wood preservatives, and lead-acid batteries. It is also a particularily corrosive and dangerous acid, with extreme environmental and health hazards if not manufactured, used, and regulated properly.Sulfuric Acid Manufacture: Analysis, Control and Optimization keeps the important topics of safety and regulation at the forefront as it overviews and analyzes the process of sulfuric acid manufacture.The first nine chapters focus on the chemical plant processes involved in industrial acidmaking, with considerable data input from the authors' industrial colleagues. The last 15 chapters are dedicated to the mathematical analysis of acidmaking.Both Authors bring years of hands-on knowledge and experience to the work, making it an exceptional reference for anyone involved in sulfuric acid research and/or manufacture.
MoreTable of Contents:
Chapter 1: Overview
Chapter 2: Production and Consumption
Chapter 3: Sulfur Burning
Chapter 4: Metallurgical Offgas Cooling and Cleaning
Chapter 5: Regeneration of Spent Sulfuric Acid
Chapter 6: Dehydrating Air and Gases with Strong Sulfuric Acid
Chapter 7: Catalytic Oxidation of SO2 to SO3
Chapter 8: SO2 Oxidation Catalyst and Catalyst Beds
Chapter 9: Production of H2SO4(?) from SO3(g)
Chapter 10: Oxidation of SO2 to SO3 - Equilibrium Curves
Chapter 11: SO2 Oxidation Heatup Paths
Chapter 12: Maximum SO2 Oxidation: Heatup Path-Equilibrium Curve Intercepts
Chapter 13: Cooling 1st Catalyst Bed Exit Gas
Chapter 14: 2nd Catalyst Bed Heatup Path
Chapter 15: Maximum SO2 Oxidation in a 2nd Catalyst Bed
Chapter 16: 3rd Catalyst Bed SO2 Oxidation
Chapter 17: SO3 and CO2 in Feed Gas
Chapter 18: 3 Catalyst Bed Acid Plant
Chapter 19: After-H2SO4-Making SO2Oxidation
Chapter 20: Optimum Double Contact Acidmaking
Chapter 21: Enthalpies and Enthalpy Transfers
Chapter 22: Control of Gas Temperature by Bypassing
Chapter 23: H2SO4 Making
Chapter 24: Acid Temperature Control and Heat Recovery
Appendix A: Sulfuric Acid Properties
Appendix B: Derivation of Equilibrium Equation (10.12)
Appendix C: Free Energy Equations for Equilibrium Curve Calculations
Appendix D: Preparation of Fig. 10.2 Equilibrium Curve
Appendix E: Proof that Volume%= Mole% (for Ideal Gases)
Appendix F: Effect of CO2 and Ar on Equilibrium Equations (None)
Appendix G: Enthalpy Equations for Heatup Path Calculations
Appendix H: Matrix Solving Using Tables 11.2 and 14.2 as Examples
Appendix I: Enthalpy Equations in Heatup Path Matrix Cells
Appendix J: Heatup Path-Equilibrium Curve Intercept Calculations
Appendix K: 2nd Catalyst Bed Heatup Path Calculations
Appendix L: Equilibrium Equation for Multi-Catalyst Bed SO2 Oxidation
Appendix M: 2nd Catalyst Bed Intercept Calculations
Appendix N: 3
Appendix O: 3rd Catalyst Bed Intercept Worksheet
Appendix P: Effect of SO3 in Fig. 10.1 Feed Gas on Equilibrium Equations
Appendix Q: SO3-in-Feed-Gas Intercept Worksheet
Appendix R: CO2- and SO3-in-Feed-Gas Intercept Worksheet
Appendix S: 3-Catalyst-Bed 'Converter' Calculations#
Appendix T: Worksheet for Calculating After-Intermediate-H2SO4-Making Heatup Path Equilibrium Curve Intercepts
Appendix U: After-H2SO4-Making SO2 Oxidation with SO3 and CO2 in Input Gas
Appendix V: Moist Air in H2SO4 Making Calculations
Appendix W: Calculation of H2SO4 Making Tower Mass Flows
Answers to Numerical Problems
Author Index
Index
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