Structural Order-Disorder and Ionic Conductivity of Novel Hexagonal Perovskite-Related Oxides
Series: Springer Theses;
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Product details:
- Publisher Springer Nature Singapore
- Date of Publication 16 May 2026
- ISBN 9789819206377
- Binding Hardback
- No. of pages204 pages
- Size 235x155 mm
- Language English
- Illustrations XXII, 204 p. 114 illus., 98 illus. in color. 700
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Long description:
"
This thesis presents relationships between ionic conductivity and crystal structure of hexagonal perovskite revealed from a new perspective: order and disorder. It describes three state-of-art research results in the new area of structure of ionic conductors, hexagonal perovskite-related structures, based on a new viewpoint of structural order/disorder. The first is occupational disorder of oxygen atoms and ionic conductivity in Ba3MNbO8.5 (M = Mo, W) investigated by high-temperature neutron diffraction and the maximum-entropy method. Second is the hidden chemical order in disordered Ba7Nb4MoO20·0.15H2O that was discovered by a combined technique of resonant X-ray diffraction and solid-state nuclear magnetic resonance. This combined technique was named as RXRD/NMR method. The third is the discovery of a rubidium-containing oxide-ion conductor with large positional disorder of oxygen atoms. This volume gives readers two outlooks. One is proposed guidelines for the search and development of ionic conductors with hexagonal perovskite-related structures. Another is future application of analyses for order/disorder used in this study, especially the RXRD/NMR method.
" MoreTable of Contents:
Introduction of ionic conductors and order disorder in the crystal.- Techniques and Terms.- Oxide ion occupational disorder, conductivity, and diffusion pathways in Ba3MNbO8 5 M W, Mo.- Hidden Occupational Order in Disordered Ba7Nb4MoO20 Revealed by a combined technique of Resonant X ray Diffraction and Solid State NMR.- Discovery of a Rubidium Containing Oxide Ion Conductor with Hexagonal Perovskite Related Structure.- Summary and Appendix.
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