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  • Mechanisms of Atmospheric Oxidation of the Oxygenates

    Mechanisms of Atmospheric Oxidation of the Oxygenates by Calvert, Jack; Mellouki, Abdelwahid; Orlando, John;

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    Product details:

    • Publisher OUP USA
    • Date of Publication 29 September 2011

    • ISBN 9780199767076
    • Binding Hardback
    • No. of pages1634 pages
    • Size 160x236x88 mm
    • Weight 2509 g
    • Language English
    • Illustrations 462 illus.
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    Short description:

    Prepared by an international team of eminent atmospheric scientists, "Mechanisms of Atmospheric Oxidation of the Oxygenates" is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere.

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    Long description:

    Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues.

    This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.

    I doubt that even the most keen atmospheric chemists will find the book a page turner but I think anyone that has a copy will find themselves (as I have) coming back to it regularly.

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    Table of Contents:

    The Oxygenates: Their Properties, Sources, and Use as Alternative Fuels
    Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Alcohols
    Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Ethers
    Rate Coefficients and Mechanisms for the Atmospheric Oxidation
    Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Ketonesof the Aldehydes
    Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Organic Acids
    Rate Coefficients and Mechanisms for the Atmospheric Oxidation of the Esters
    Rate Coefficients and Mechanisms for Atmospheric Oxidation of N-Atom-Containing Oxygenates
    Mechanisms of Photodissociation of the Sunlight-Absorbing Oxygenates
    The Influence of Oxygenates on the Atmospheric Chemistry of Urban, Rural, and Global Environments
    Appendix. Structures of the Oxygenates Discussed in This Report

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