Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid?Solid Interface
Series:
Springer Theses;
Edition number: 1st ed. 2020
Publisher: Springer
Date of Publication: 22 February 2020
Number of Volumes: 1 pieces, Book
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Product details:
| ISBN13: | 9789811531910 |
| ISBN10: | 9811531919 |
| Binding: | Hardback |
| No. of pages: | 83 pages |
| Size: | 235x155 mm |
| Weight: | 454 g |
| Language: | English |
| Illustrations: | 8 Illustrations, black & white; 59 Illustrations, color; 30 Tables, color |
| 0 |
Category:
Short description:
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid?solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid?solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid?solid interfaces not found in solutions.
Detailed results are provided for new chemical reactions at liquid?solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid?solid interface.
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid?solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid?solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid?solid interfaces not found in solutions.
Detailed results are provided for new chemical reactions at liquid?solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid?solid interface.
Long description:
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid?solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid?solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid?solid interfaces not found in solutions.
Detailed results are provided for new chemical reactions at liquid?solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid?solid interface.
Table of Contents:
1. Introduction.
- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid
-Solid Interface.
- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self
-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution.
- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers.
- 5. Conclusions.
- 6. Experimental Section.
- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid
-Solid Interface.
- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self
-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution.
- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers.
- 5. Conclusions.
- 6. Experimental Section.
