Electronic and Optical Properties of Conjugated Polymers
Series: International Series of Monographs on Physics; 159;
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Product details:
- Edition number 2
- Publisher OUP Oxford
- Date of Publication 4 April 2013
- ISBN 9780199677467
- Binding Hardback
- No. of pages320 pages
- Size 248x192x23 mm
- Weight 665 g
- Language English
- Illustrations 133 b/w illustrations 0
Categories
Short description:
Conjugated polymers have important technological applications including solar cells and light emitting devices. They are active components in many important biological processes. This book describes and explains the electronic and optical properties of conjugated polymers by developing theoretical models to understand the key electronic states.
MoreLong description:
Conjugated polymers have important technological applications, including solar cells and light emitting devices. They are also active components in many important biological processes. In recent years there have been significant advances in our understanding of these systems, owing to both improved experimental measurements and the development of advanced computational techniques.
The aim of this book is to describe and explain the electronic and optical properties of conjugated polymers. It focuses on the three key roles of electron-electron interactions, electron-nuclear coupling, and disorder in determining the character of the electronic states, and it relates these properties to experimental observations in real systems.
A number of important optical and electronic processes in conjugated polymers are also described. The second edition has a more extended discussion of excitons in conjugated polymers. There is also a new chapter on the static and dynamical localization of excitons.
Review from previous edition William Barford's Electronic and Optical Properties of Conjugated Polymers is a theoretical complement to the high experimental culture of British research on conjugated polymers.
Table of Contents:
Introduction to conjugated polymers
Π-electron theories of conjugated polymers
Noninteracting electrons
Electron-nuclear coupling I: Noninteracting electrons
Interacting electrons
Excitons in conjugated polymers
Electron-nuclear coupling II: Interacting electrons
Linear polyenes and trans-polyacetylene
Light emitting polymers
Exciton localization in disordered polymers
Optical processes in conjugated polymers
Excitonic processes in conjugated polymers
Epilogue
Appendix A: Dirac bra-ket operator representation of one-particle Hamiltonians
Appendix B: Electron-hole symmetry and average occupation number
Appendix C: Single-particle eigensolutions of a periodic polymer chain
Appendix D: The Holstein model
Appendix E: Derivation of the effective-particle Schrödinger equation
Appendix F: Hydrogenic solutions of the effective-particle exciton models
Appendix G: Valence-bond description of benzene
Appendix H: Derivation of the Frenkel exciton Hamiltonian
Appendix I: Evaluation of the electronic transition dipole moments
Appendix J: Spin-orbit coupling in Π-conjugated polymers
Appendix K: Derivation of the line dipole approximation
Appendix L: Direct configuration interaction-singles calculations
Appendix M: Density matrix renormalization group method
