A User's Perspective of Magnetochemistry
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Product details:
- Publisher Wiley VCH
- Date of Publication 19 March 2026
- ISBN 9783527327072
- Binding Hardback
- No. of pages350 pages
- Size 240x170 mm
- Language English 700
Categories
Short description:
An introduction to the fundamental concepts of molecular magnetism and how to apply them. The reader is instructed how to analyze and characterize molecular–based magnetic materials and how to calculate magnetic properties. The software is downloadable from the authors' website.
MoreLong description:
Authored by a perfect interdisciplinary team of top scientists, this textbook teaches the fundamentals of molecular magnetism while showing how to apply these concepts with the aid of computer programs. The book and the accompanying software enable readers to acquire and translate magnetic data for molecular magnetic materials into chemically meaningful information.
The up–to–date software can be downloaded from the authors' website.
Both a teaching and research tool for advanced masters and PhD students, lecturers and researchers new to the field.
Magnets are useful for many things, not only for sticking pictures on refrigerator doors!
Even molecules can act as tiny magnets, and there has been a rapid increase in the amount of research investigating their huge technological potential. They could be used in the next generation of smaller and faster computers and for efficient data storage, since molecular magnets allow a maximum of memory to be packed into a small space.
Authored by a perfect interdisciplinary team of top scientists, this textbook teaches the fundamentals of molecular magnetism while showing how to apply these concepts with the aid of computer programs.
From the contents:
* Units, concepts and definitions
* Theoretical background
* Fundamental magnetic behavior
* Single ion systems
* Exchange–coupled systems
* Calculation of the experimental quantities
* Measuring the magnetic moment
* Spectroscopic techniques
* Chemical design
The book and the accompanying software, which may be downloaded from the authors' website, enable readers to acquire and translate magnetic data for molecular magnetic materials into chemically meaningful information.
Both a teaching and research tool for advanced masters and PhD students, lecturers and researchers new to the field.
Table of Contents:
INTRODUCTION
UNITS, CONCEPTS AND DEFINITIONS
Fundamental Equations of Magnetism written down in both SI and c.g.s. e.m.u. units.
Definition of the following terms: permeability, magnetic field, magnetic intensity, magnetisation, partition function, magnetic torque, magnetic specific heat, magnetic susceptibility, diamagnetism and paramagnetism, ferromagnetism, antiferromagnetism, ferrimagnetism, the effective magnetic moment
THEORETICAL BACKGROUND
Angular Momenta
Basis states and Vector Coupling Coefficients
Operator Equivalents and the Concept of the Spin–Hamiltonian
FUNDAMENTAL MAGNETIC BEHAVIOUR
Derivation and Application of the Van Vleck Equation
The Curie Law
Temperature Independent Paramagnetism
The Brillouin Function
Bleaney–Bowers Equation
Simple examples of Kambe's approach
SINGLE ION SYSTEMS
Correlation between the effective magnetic moment and the electronic structure of transition metal complexes
Describing and understanding Magnetic Anisotropy
EXCHANGE–COUPLED SYSTEMS
The Sign and Magnitude of Exchange Coupling Parameters
Small Magnetic Clusters
Large Magnetic Clusters: Heisenberg interactions
Large Magnetic Clusters: Giant Spin Approximation
Long Range Order and Molecular Field Theory
CALCULATION OF THE EXPERIMENTAL QUANTITIES
General Numerical Method for the Calculation of Experimental Quantities
Calculation of the Magnetic Moment
High–Temperature Expansion of the Partition Function
Spin Coupling and Kambe?s Method
Sparse–Matrix Techniques
EXPERIMENTAL METHODS OF MEASURING THE MAGNETIC MOMENT, DISCUSSION OF PRO AND CONS
The SQUID Magnetometer
AC Susceptibility
Thermodynamic Measurements
Measuring the Magnetic Torque
SPECTROSCOPIC TECHNIQUES
Electron Paramagnetic Resonance
Inelastic Neutron Scattering
CHEMICAL DESIGN
Engineering single site anisotropies
Bridging motifs and couplings in dinuclear systems
Ferromagnetism through orthogonal orbitals
Designing chains and rings
Taking advantage of spin frustration
Cluster synthesis – self assembly versus control
Canted spins – adding it all up
APPENDICES
Fundamentals of Matrix Mechanics
Perturbation Theory
Group Theory and the Wigner–Eckhart Theorem
Free Ions, Ligand Field Theory and the Angular Overlap Model
