Short description:

The electrocatalytic reduction of CO? into high-value multi-carbon products represents a pathway toward carbon neutrality and sustainable chemical production. The transition from lab-scale studies to industrial-scale implementation helps bridge the gap theory and practice.

This book explores the mechanism and functional design of electrocatalysts for CO? electroreduction, focusing on bridging the gap between lab-scale research and industrial implementation. It investigates the role of grain boundary structures, oxidation states, and interfacial microenvironments in stabilizing Cu-based catalysts, which improve the production of multi-carbon products. Additionally, this work introduces new approaches to modulate copper oxidation states, leading to improved catalytic performance.

By integrating fundamental insights with industrial feasibility, this book offers a guide for researchers and engineers to developing next-generation CO? electrolysis technologies, thereby contributing to carbon-neutral chemical manufacturing and sustainable energy solutions. 

In addition, this book:

• Bridges between lab-scale studies and industrial implementation, offering guidance for actual applications


• Provides information on catalysts’ design and modulation to help improve their selectivity and stability


• Serves as a resource for professionals working towards sustainable and carbon-neutral chemical manufacturing

Long description:

The electrocatalytic reduction of CO? into high-value multi-carbon products represents a crucial pathway toward achieving carbon neutrality and sustainable chemical production. The transition from lab-scale studies to industrial-scale implementation is imperative to bridge the gap between fundamental mechanistic insights and practical applications.

This book explores the mechanistic understanding and functional design of electrocatalysts for CO? electroreduction, focusing on bridging the gap between lab-scale research and industrial-scale implementation. It systematically investigates the role of grain boundary structures, oxidation states, and interfacial microenvironments in stabilizing Cu-based catalysts, thereby enhancing the selective production of multi-carbon products. By integrating oxidation and alloying strategies, this work introduces new approaches to modulate copper oxidation states, leading to improved catalytic performance. Advanced characterization techniques, including in situ multimodal spectroscopy, provide insights into the electrochemical stability of Cu^δ? species and their impact on reaction pathways.

Beyond catalyst design, this book extends the discussion to CO? electrolyzer configurations, emphasizing membrane electrode assemblies and gas diffusion electrode engineering for scalable applications. The introduction of functionalized carbon black to modulate the interfacial environment, effectively suppresses the hydrogen evolution reaction, stabilizing active Cu^δ? species and promoting ethylene production with high Faradaic efficiency.

By integrating fundamental insights with industrial feasibility, this book offers a comprehensive guide for researchers and engineers developing next-generation CO? electrolysis technologies, contributing to carbon-neutral chemical manufacturing and sustainable energy solutions.

Table of Contents:

Introduction.- Literature Review.- Enhanced CO2-to-CH4 conversion via grain boundaries oxidation effect in CuAg systems.- Revealing real active sites in intricate grain boundaries assemblies on electroreduction of CO2 to C2+ products.- Stabilized Cuδ+-OH species on in situ reconstructed Cu nanoparticles for CO2-to-C2H4 conversion in neutral media.- Conclusion and Outlook.