Carbocation Chemistry
Applications in Organic Synthesis
Series: New Directions in Organic & Biological Chemistry;
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Product details:
- Edition number 1
- Publisher CRC Press
- Date of Publication 10 December 2019
- ISBN 9780367873462
- Binding Paperback
- No. of pages224 pages
- Size 234x156 mm
- Weight 410 g
- Language English 61
Categories
Short description:
Organic chemistry is the science of carbon-containing compounds. There are four major types of reactive intermediates in organic chemistry: carbocations, carboanions, radicals and carbenes. Therefore, carbocation chemistry is not only fundamental to the advancement of organic chemistry, it also has found widespread applications in organic synthe
MoreLong description:
Carbocation chemistry is not only fundamental to the advancement of organic chemistry, it also has found widespread applications in organic synthesis. It is not an exaggeration to say that carbocation chemistry is part of the foundation of organic chemistry. Carbocation Chemistry: Applications in Organic Synthesis provides a panoramic view of carbocation chemistry with an emphasis on synthetic applications.
This book is an invaluable tool for organic, medicinal and analytical chemists, including those working in biochemistry as well as the petroleum, plastics and pharmaceutical industries. It is also suitable for upper level undergraduates and graduates in organic chemistry, biochemistry and medicinal chemistry.
MoreTable of Contents:
Chapter 1. Introduction
- Nomenclature, Structure, and Stability
- Generation of Carbocations
- The Non-Classical Ion Controversy
- Electrophilic Addition to Alkenes
- Electrophilic Aromatic Substitution
- Elimination reactions
- Rearrangement Reactions of Carbocations
- References
Chapter 2. Nucleophilic Aliphatic Substitution ? SN1
- Introduction
- -Activated Alcohols?Br?nsted Acids
- -Activated Alcohols?Lewis Acids
- Alkylation of Aldehydes and Ketones
- Glycosylation
- Friedel?Crafts Alkylation and Acylation
- Electrophilic Fluorination Using Fluoronium Ion
- Miscellaneous SN1-related Reactions
- References
Chapter 3. Nucleophilic Aliphatic Substitution ? SN2
- Construction of Quaternary Stereogenic Centers
- Sulfur Chemistry
- Organometallic Chemistry
- Macrocyclization
- Glycosylation
- Nucleoside Analogues
- N-Alkylation
- Cyclotetraphosphazenes
- Conformationally Locked Tetrahydropyran Ring
- The Ionic Liquid Effect
- Silver Chemistry
- References
Chapter 4. Electrophilic Addition to Alkenes
- Introduction
- Cyclopropanation
- Hydroboration/Oxidation
- The Pauson?Khand Reaction
- Prins Reaction
- Schmidt Reaction
- Halogenation
- Oxymercuration/Reduction
- Epoxidation
- Gold-Catalyzed Alkyne Hydration
- Conclusion
- References
Chapter 5. Electrophilic Aromatic Substitution
- Introduction
- Nitration
- Halogenation
- Friedel?Crafts Alkylation
- Friede More
Carbocation Chemistry: Applications in Organic Synthesis
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